Search Result from the June 2009 Issue
| Return to Search | Return to Results |
FEASIBILITY STUDY FOR THE REMEDIATION OF GROUNDWATER CONTAMINATED BY ORGANOLEAD COMPOUNDSAndreottola, G., L. Dallago, and E. Ferrarese, Univ. degli Studi di Trento, Italy. Journal of Hazardous Materials, Vol 156 Nos 1-3, p 488-498, 2008
The effectiveness of chemical oxidation, advanced oxidation processes
(AOPs), and adsorption on granular activated carbon (GAC) was evaluated for
the ex situ remediation of a groundwater contaminated by organolead compounds,
including tetraethyl lead (TEL), triethyl lead (TREL) and diethyl lead (DEL).
The researchers collected groundwater from the site of a former
tetraalkyllead-producing company in Trento, Italy. The samples showed an
average total organic lead (TOL) content about 95.1 ug/L (TEL 0.5 ug/L, TREL
86.4 ug/L, DEL 8.3 ug/L). The main goal was to find out which method was most
effective in reducing the pollutant content. The laboratory tests included
chemical oxidation tests with different reactants (hydrogen peroxide, modified
Fenton's reagent, potassium permanganate, activated potassium persulfate,
oxygen, and combinations of potassium permanganate and modified Fenton's
reagent); AOPs with ozone, UV radiation, and hydrogen peroxide; and filtration
on GAC. A combination of chemical and physical treatments also was tested,
with GAC filtration followed by chemical oxidation. The treatments exhibiting
the best remediation performances were chemical oxidation with modified
Fenton's reagent, AOPs with hydrogen peroxide and ozone (perozone), AOPs with
hydrogen peroxide and UV radiation, and a coupled treatment of activated
carbon filtration followed by chemical oxidation with perozone. All these
treatments showed a 90% TOL removal, with excellent removals of both TEL and
TREL, and with final DEL concentrations below 5 ug/L. Background information
on this study can be found in E. Ferrarese's 2008 dissertation at
http://www.ing.unitn.it/dica/eng/monographs/pdf/Monographs_11.pdf
The Technology Innovation News Survey welcomes your comments and
suggestions, as well as information about errors for correction. Please
contact Michael Adam of the U.S. EPA Office of Superfund and Emergency Management at adam.michael@epa.gov or (703) 603-9915
with any comments, suggestions, or corrections.
Mention of non-EPA documents, presentations, or papers does not constitute a U.S. EPA endorsement of their contents, only an acknowledgment that they exist and may be relevant to the Technology Innovation News Survey audience.



